Indium-mediated consecutive 1,2-shift reaction and regioselective allylation of vinyl epoxides |
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| Authors: | Byung Kyu OhJoo Hwan Cha Yong Seo ChoKyung Il Choi Hun Yeong KohMoon Ho Chang Ae Nim Pae |
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| Institution: | Biochemicals Research Center, Korea Institute of Science and Technology, PO Box 131 Cheongryang, Seoul 130-650, Republic of Korea |
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| Abstract: | Allyl indium, prepared from allyl bromide and indium metal in aprotic solvent, reacts with terminal vinyl epoxides at room temperature to afford various bishomoallyl alcohols in moderate to high yields via consecutive 1,2-shift reaction and regioselective allylation. |
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