Intramolecular oxyselenenylation and deselenenylation reactions in water, conducted by employing polymer-supported arylselenenyl bromide |
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| Authors: | Ken-ichi Fujita Shigeru HashimotoAkihiro Oishi Yoichi Taguchi |
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| Institution: | National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1, Higashi, Tsukuba, Ibaraki 305-8565, Japan |
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| Abstract: | After immobilizing arylselenenyl bromide on polymer resin, the oxyselenenylation reaction of olefin was carried out in water. An amphiphilic polymer-supported arylselenenyl bromide was employed, and various intramolecular oxyselenenylation and deselenenylation reactions proceeded smoothly in water in fair chemical yields (up to an 83% yield). |
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| Keywords: | polymer-supported selenium solid-phase oxyselenenylation water |
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