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Enantioselective synthesis of d-ribo-(2S,3S,4R)-C18-phytosphingosine using double stereodifferentiation
Authors:S.Vasudeva NaiduPradeep Kumar
Affiliation:Division of Organic Chemistry: Technology, National Chemical Laboratory, Pune-411008, India
Abstract:An enantioselective synthesis of d-ribo-C18-phytosphingosine as its tetraacetate derivative 10, starting from d-mannitol and employing the Sharpless asymmetric dihydroxylation reaction on allylic alcohol 6 as the key step, is described.
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