Enantioselective synthesis of d-ribo-(2S,3S,4R)-C18-phytosphingosine using double stereodifferentiation |
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| Authors: | SVasudeva NaiduPradeep Kumar |
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| Institution: | Division of Organic Chemistry: Technology, National Chemical Laboratory, Pune-411008, India |
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| Abstract: | An enantioselective synthesis of d-ribo-C18-phytosphingosine as its tetraacetate derivative 10, starting from d-mannitol and employing the Sharpless asymmetric dihydroxylation reaction on allylic alcohol 6 as the key step, is described. |
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