Unexpected formation of 4,4,6-trimethyl-2-oxo-1-phenyl-1,2,3,4-tetrahydropyridine-3-carbonitrile via Tandem Knoevenagel condensation-Michael addition-intramolecular cyclization |
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Authors: | A. A. Nikishin V. D. Dyachenko A. N. Chernega |
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Affiliation: | 1.Taras Shevchenko Lugansk National University,Lugansk,Ukraine;2.Institute of Organic Chemistry,National Academy of Sciences of Ukraine,Kiev,Ukraine |
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Abstract: | Knoevenagel condensation (Cope version) of acetone with cyanoacetanilide resulted in the formation of 4,4,6-trimethyl-2-oxo-1-phenyl-1,2,3,4-tetrahydropyridine-3-carbonitrile whose structure was determined by X-ray analysis. |
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