Solvothermal synthesis and structural characterization of a novel erbium(III)-carboxylate polymeric complex |
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| Authors: | Q. B. Bo Z. X. Sun Y. L. Sheng Z. W. Zhang G. X. Sun C. L. Chen Y. X. Li D. Q. Wang |
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| Affiliation: | (1) Institute of Chemistry and Chemical Engineering, Jinan University, No.106, Jiwei Road, Jinan, 250022, Shandong, P.R. China;(2) Department of Chemistry, Liaocheng University, Liaocheng, Shandong, 252059, P.R. China |
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| Abstract: | A novel erbium(III)-carboxylate polymeric complex [{Er(H2btec)2/4(btec)3/6(H2O)}·2H2O] n , simplified as ECPC, (H4btec=1,2,4,5-benzenetetracarboxylic acid) was synthesized under solvothermal conditions (H2O/acetic acid). ECPC obtained was characterized by differential thermal analysis/thermogravimetry (DTA/TG), single-crystal X-ray diffraction, elemental analysis and FT-IR analysis techniques. The result of single-crystal X-ray diffraction analysis shows that the ECPC crystallizes in monoclinic symmetry, and the space group P2(1)/n, a=10.6933(15) Å, b=7.1243(10) Å, c=17.092(2) Å, α=γ=90°, β=97.109(2)°, V=1292.1(3) Å3, Z=4, R 1=0.0286, wR 2=0.0686. ECPC demonstrates a 3-D supramolecular framework containing nine-coordinate erbium centers and channels. The uncoordinated water molecules occupy the channels in ECPC. The results of TG/DTA, IR and elemental analysis performed also give positive information of the proposed crystal structure. |
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| Keywords: | Solvothermal synthesis Erbium Carboxylate Polymeric complex Crystal structure |
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