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Determination of hydroxyl radicals from photolysis of Fe(III)-pyruvate complexes in homogeneous aqueous solution ? |
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| Authors: | Lei Wang Changbo Zhang Feng Wu Nansheng Deng Evgeni M. Glebov Nikolai M. Bazhin |
| Affiliation: | (1) Department of Environmental Science, Wuhan University, Wuhan, 430072, P. R. China;(2) Department of Environmental Science, Wuhan University, Wuhan, 430072, P. R. China;(3) Department of Environmental Science, Wuhan University, Wuhan, 430072, P. R. China;(4) Department of Environmental Science, Wuhan University, Wuhan, 430072, P. R. China;(5) Institute of Chemical Kinetics and Combustion, Novosibirsk 630090, Russia;(6) Institute of Chemical Kinetics and Combustion, Novosibirsk 630090, Russia |
| Abstract: | Summary Benzene was used as a probe to detect ·OH produced by photolysis of Fe(III)-pyruvate complexes in a homogeneous system. The Fe(III)-Pyr system was found to be not catalytic. Influence of pH, temperature, as well as the concentration of Fe(III) and pyruvate (Pyr) on the ·OH yield was investigated. |
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