A mechanistic rationalization of unusual kinetic behavior in proline-mediated C-O and C-N bond-forming reactions |
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| Authors: | Mathew Suju P Klussmann Martin Iwamura Hiroshi Wells David H Armstrong Alan Blackmond Donna G |
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| Institution: | Department of Chemistry, Imperial College, London, UK SW7 2AZ. |
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| Abstract: | Kinetic evidence supports the role of the reaction product in the catalytic cycle of proline-mediated alpha-aminoxylation and alpha-amination reactions, providing both design principles as well as a model for the evolution of efficiency in catalysis. |
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