Komplexe von N,N-Di-(β-hydroxyäthyl)-dithiocarbaminat mit Übergangs- und Nachübergangs-Elementen

The complexation tendencies of N,N-di-(-hydroxyethyl)-dithiocarbamic acid DEADTCH, (CH₂CH₂OH)₂NCSSH] towards a large number of metal ions have been examined. The complexes formed with transition and post-transition metal ions in slightly acidic and neutral solutions have the general formulaM(DEADTC) _x, wherex is the valence state of the metal,M=Cr(III), Fe(III), Co(III), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Tl(I), and Tl(III). In addition the interesting mixed ligand complex ClHg(DEADTC) was prepared. These complexes have been characterised through X-ray, magnetic, conductance and spectral (UV and IR) measurements.