Novel U-Shaped Systems Containing an Imide-Functionalized Cleft for the Study of Solvent-Mediated Electron Transfer and Energy Transfer: Synthesis and Binding Studies |
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| Authors: | Head Oliver Look Lokan Jones Paddon-Row |
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| Affiliation: | School of Chemistry, University of New South Wales, Sydney, N.S.W., 2052 (Australia). |
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| Abstract: | A solution to the vexing problem of investigating solvent-mediated electron transfer under conditions of frozen solvent motion may be at hand with the synthesis of novel U-shaped systems such as 1 (R=CO(2)Me) and 2 (R=CH(2)OMe), in which the imide-functionalized cleft provides the point of attachment of the "solvent" molecule, either covalently or by hydrogen bonding. |
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