Regioselective synthesis of trifluoromethyl group substituted allylic amines via palladium-catalyzed allylic amination |
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| Authors: | Motoi Kawatsura |
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| Institution: | Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori 680-8552, Japan |
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| Abstract: | The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc)2/DPPE and Pd(π-allyl)(cod)]BF4/DPPF. The selective formation of the γ-product was attained by Pd(OAc)2/DPPE, while the α-product was obtained using Pd(π-allyl)(cod)]BF4/DPPF. |
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| Keywords: | Palladium Allylic amination Regioselectivity Fluorine |
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