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Preparation of 1,2,4,5‐tetrasubstituted imidazoles over magnetic core–shell titanium dioxide nanoparticles
Authors:Ardeshir Khazaei  Ahmad Reza Moosavi‐Zare  Fatemeh Gholami  Vahid Khakyzadeh
Institution:1. Faculty of Chemistry, Bu‐Ali Sina University, Hamedan, IR, Iran;2. Sayyed Jamaleddin Asadabadi University, Asadabad, IR, Iran;3. Department of Chemistry, K. N. Toosi University of Technology, Tehran, IR, Iran
Abstract:Magnetic core–shell titanium dioxide nanoparticles (Fe3O4@SiO2@TiO2) were applied for the efficient preparation of 1,2,4,5‐tetrasubstituted imidazole derivatives by the one‐pot multi‐component condensation of benzil with aldehydes, primary amines and ammonium acetate under solvent‐free conditions. The catalyst was synthesized and studied using several techniques including X‐ray diffraction, transmission electron microscopy, field‐emission scanning electron microscopy and energy‐dispersive X‐ray spectroscopy. Copyright © 2016 John Wiley & Sons, Ltd.
Keywords:magnetic core–  shell titanium dioxide  nanoparticle  solvent‐free  imidazole  multi‐component
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