| 具有经典ACO拓扑开放结构的三维多孔多钒氧酸盐的水热合成和晶体结构 |
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| 引用本文： | 郭九玉,张志斌,颜大伟,朱敦如,许 岩.具有经典ACO拓扑开放结构的三维多孔多钒氧酸盐的水热合成和晶体结构[J].无机化学学报,2011,27(10):2100-2104. |
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| 作者姓名： | 郭九玉 张志斌 颜大伟 朱敦如 许 岩 |
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| 作者单位： | 南京工业大学化学化工学院,材料化学工程国家重点实验室,南京210009 |
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| 基金项目： | 国家自然科学基金(No.20971068)资助项目 |
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| 摘 要： | 本文采用水热技术合成了一种具有经典ACO拓扑结构的多钒氧酸盐{Cu4(VⅣ11VⅤ7O42(PO4))(C3H10N2)8]·4H2O}n (1，C3H10N2=1，2-丙二胺)，并且通过元素分析、红外、热重、单晶X-射线衍射对化合物1进行了表征。晶体学分析表明，阴离子簇VⅣ11VⅤ7O42(PO4)]8-与8个过渡金属配合物阳离子Cu(C3H10N2)2]2+相连而产生具有经典ACO拓扑结构的三维孔道结构。化合物1为四方晶系，P4/nnc空间群，a=b=1.505 91(10) nm，c=1.871 3(3) nm，V=4.243 8(7) nm3，Z=2。化合物1沿c轴方向具有0.753 nm×0.753 nm孔道。
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| 关 键 词： | 水热合成 多钒氧酸盐 晶体结构 ACO拓扑结构 |
Hydrothermal Synthesis and Crystal Structure of a Three-Dimensional Porous Polyoxovanadate with Typical ACO Topological Open Frameworks |
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| GUO Jiu-Yu,ZHANG Zhi-Bin,YAN Da-Wei,ZHU Dun-Ru and XU Yan.Hydrothermal Synthesis and Crystal Structure of a Three-Dimensional Porous Polyoxovanadate with Typical ACO Topological Open Frameworks[J].Chinese Journal of Inorganic Chemistry,2011,27(10):2100-2104. |
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| Authors: | GUO Jiu-Yu ZHANG Zhi-Bin YAN Da-Wei ZHU Dun-Ru and XU Yan |
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| Institution: | College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China,College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China,College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China,College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China and College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China |
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| Abstract: | |
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| Keywords: | hydrothermal synthesis polyoxovanadate crystal structure ACO topological open framework |
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