| 原位溶解-沉积法制备高可见光活性BiOI/Bi2O3光催化剂 |
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| 引用本文： | 刘素芹,戴高鹏,梁 英,刘华俊,张 兴.原位溶解-沉积法制备高可见光活性BiOI/Bi2O3光催化剂[J].无机化学学报,2011,27(10):1964-1968. |
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| 作者姓名： | 刘素芹 戴高鹏 梁 英 刘华俊 张 兴 |
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| 作者单位： | 1. 襄樊学院化学与食品科学学院,襄樊441O53
2. 襄樊学院化学与食品科学学院,襄樊441O53;华中科技大学化学系,武汉430074 |
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| 基金项目： | 湖北省自然科学基金(No.2008CDB014); 湖北省教育厅科学技术重大项目(No.Z20102601);湖北省教育厅(No.Q20092505)资助项目 |
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| 摘 要： | 以Bi2O3为前驱体,通过原位溶解-沉积法在KI溶液中制备了BiOI/Bi2O3光催化剂。用X射线衍射(XRD)、扫描电子显微镜(SEM)和紫外-可见漫反射光谱(UV-Vis DRS)等对样品进行了表征。结果表明Bi2O3球形颗粒紧密地贴在BiOI片上。随着KI溶液pH值的降低,Bi2O3逐渐转变为BiOI,且样品的吸收带边逐渐红移。在可见光(λ≥420 nm)下降解甲基橙,在pH=3下制备的BiOI/Bi2O3的活性最强,其原因是BiOI/Bi2O3 p-n异质结促进了光生载流子的分离。
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| 关 键 词： | BiOI/Bi2O3 原位溶解-沉积 可见光 光催化 异质结 |
Preparation of BiOI/Bi2O3 Photocatalyst with Highly Visible-Light Photocatalytic Activity by an In Situ Dissolving-Depositing Method |
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| LIU Su-Qin,DAI Gao-Peng,LIANG Ying,LIU Hua-Jun and ZHANG Xing.Preparation of BiOI/Bi2O3 Photocatalyst with Highly Visible-Light Photocatalytic Activity by an In Situ Dissolving-Depositing Method[J].Chinese Journal of Inorganic Chemistry,2011,27(10):1964-1968. |
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| Authors: | LIU Su-Qin DAI Gao-Peng LIANG Ying LIU Hua-Jun and ZHANG Xing |
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| Institution: | Department of Chemical and Food Science, Xiangfan University, Xiangfan, Hubei 441053, China,Department of Chemical and Food Science, Xiangfan University, Xiangfan, Hubei 441053, China,Department of Chemical and Food Science, Xiangfan University, Xiangfan, Hubei 441053, China,Department of Chemical and Food Science, Xiangfan University, Xiangfan, Hubei 441053, China and Department of Chemical and Food Science, Xiangfan University, Xiangfan, Hubei 441053, China; Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China |
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| Abstract: | BiOI/Bi2O3 was prepared by an in situ dissolving-depositing method with Bi2O3 as precursor.The as-prepared samples were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),and UV-Vis absorption spectroscopy.The results showed that the spherical Bi2O3 particles were compactly connected with the BiOI sheets.With the decrease of the pH value of KI solution,the Bi2O3 was gradually transformed into BiOI,and the absorption bands showed a red shift gradually.BiOI/Bi2O3 prepared at pH value of... |
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| Keywords: | BiOI/Bi2O3 in situ dissolving-depositing visible light photocatalytic heterojunction |
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