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| Synthesis and Electrochemical Properties of a New Tetraazamacrocyclic Complex of Silver (Ⅰ) | |
| 作者姓名： | Fu Xin XIE Xu Feng YU Hao ZHANGLiang ZHAO Yu Peng TIAN and Shi Sheng NI(Anhui University Hefei Anhui 230039State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 21 0093) |
| 作者单位： | Anhui University，Hefei，Anhui 230039State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing 21 0093 |
| 摘 要： | Themetalmacrocycliccomplexeswiththeirunusualoxidationstateshaveattractedmuchinterest.Silver(Il)andsi1ver(IlI)compoundsareusuallyunstab1eduetotheirstrongoxidation.Butsometetraazamacrocyclicligandscandirectlygivestablecom-plexesofsiIver(Il)throughdisproportionatedreactionofsilver(I).12fIere,wereportthesynthesisandeIectrochemicalbehaviorofanewsilver(Il)com-plexAgL(CIO')2(L=5,7,l2,l4-tetraethyl-5,l2-dimethyl-l,4,8,ll-tetraazacyclotetradec-4,l1-diene).Therelativeinformationaboutothersilver(1I… |
| 关 键 词： | Electrochemical properties novel silver (Ⅱ) complex |
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