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Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate |
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| Authors: | Armstrong David R Clegg William Dale Sophie H García-Alvarez Joaquín Harrington Ross W Hevia Eva Honeyman Gordon W Kennedy Alan R Mulvey Robert E O'Hara Charles T |
| Institution: | WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK. |
| Abstract: | In a new type of reactivity for sodium TMP-zincate (TMEDA)NaZn((t)Bu)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H). |
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