First Example of 1,3-Dipolar Cycloaddition of Carbonyl Ylides to Cyclopropenes |
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| Authors: | Molchanov A P Diev V V Kopf J Kostikov R R |
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| Institution: | (1) St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia;(2) Institut für anorganische Chemie, Hamburg, Germany |
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| Abstract: | Carbonyl ylide generated from 1-diazo-5-phenylpentane-2,5-dione in the presence of Rh2(OAc)4 reacts with 3-substituted cyclopropenes following the 1,3-dipolar cycloaddition pattern to afford substituted 9-oxatricyclo3.3.1.02,4]nonan-6-ones. |
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