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High-energy C+ ion-irradiated low-density polyethylene (LDPE): Spectroscopic and morphological investigation
Institution:1. Department of Polymer Science and Technology, 92, A.P.C. Road, Kolkata 700009, University of Calcutta, India;2. Department of Chemical Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia;3. Department for Management of Science and Technology Development, Ton Duc Thang University, Ho Chi Minh City, Viet Nam;4. Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City, Viet Nam
Abstract:The optical absorption spectra of 3.6 MeV 12C ions irradiated low-density polyethylene (LDPE) show the gradual increase in the optical absorption and the shift from the near UV to the visible region with increase in ion fluence. The increase in absorption may be attributed to the generation of a conjugated system of bonds, which are also corroborated by FTIR. Scanning electron microscopic (SEM) studies reveal that the formation of linear network structure occurred at relatively lower ion fluence of 5×1013 ions/cm2.
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