Synthesis and crystal structure of 1-ethyl-3-(phenyl)-1,2,3-triazolium percholorate |
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| Authors: | Beeranahally H Doreswamy Madegowda Mahendra Sridhar M Anandalwar Javaregowda S Prasad Kempegowda Mantelingu Basappa Kanchugarakoppal S Rangappa |
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| Institution: | (1) Department of Studies in Physics, University of Mysore, 570 006 Manasagangotri, Mysore, India;(2) Department of Studies in Chemistry, University of Mysore, 570 006 Manasagangotri, Mysore, India |
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| Abstract: | The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-ethyl-3-(phenyl)-1,2,3-triazolium perchlorate (6+). The title compound C10H14Cl N3O4 was isolated and structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P21/c with cell parameters a=6.697(4) Å, b=9.724(9) Å, c=19.844(2) Å and Z=4. The final residual factor is R1=0.0471 for 1545 reflections with I>2σ(I). The structure exhibits intermolecular hydrogen bonds. |
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| Keywords: | Nitrenium ions Carbenes Triazolium perchlorates Crystal structure |
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