Synthesis of analogs of ecdysteroids containing an isoxaline ring in the side chain |
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Authors: | R. P. Litvinovskaya S. V. Drach G. A. Zhilitskaya V. A. Khripach |
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Affiliation: | (1) Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, Minsk, 220141, Belarus |
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Abstract: | Starting with poststerone a synthesis was performed of ecdysteroid analogs containing an isoxaline ring in the side chain. The key stages of the route to the target products were Normant reaction and the subsequent 1,3-dipolar cycloaddition of nitrile oxides to 20-hydroxy-20-vinylsteroids. |
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