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3-丙烯酰胺基-9-乙基咔唑/碘鎓盐体系敏化甲基丙烯酸甲酯光聚合
引用本文:潘卉,赵纪冬,关会立,李润明,高青雨. 3-丙烯酰胺基-9-乙基咔唑/碘鎓盐体系敏化甲基丙烯酸甲酯光聚合[J]. 化学研究, 2001, 12(1): 49-51
作者姓名:潘卉  赵纪冬  关会立  李润明  高青雨
作者单位:河南大学润滑与功能材料实验室,
基金项目:河南省自然科学基金!资助项目 ( 199915 0 0 2 5 )
摘    要:研究了 3_丙烯酰胺基_9_乙基咔唑 (AAECZ) /氯化二苯基碘钅翁盐 (DPIOC)组成的光敏引发体系引发的甲基丙烯酸甲酯 (MMA)光聚合 ,并研究了各因素对聚合速率的影响 ,得到了聚合动力学方程 ;讨论了温度对聚合反应的影响 ,并探讨了引发机理

关 键 词:3-丙烯酰胺基-9-乙基咔唑  二苯基碘鎓盐  甲基丙烯酸甲酯  光聚合
文章编号:1008-1011(2001)01-0049-03
修稿时间:2000-10-09

The Photopolymerization of Methyl Methacrylate Initiated by 3-Acrylamide-9-Ethylcarbazole and Diphenyliodomium Salt
PAN Hui,ZHAO Ji-dong,GUAN Hui-li,LI Run-ming,GAO Qing-yu. The Photopolymerization of Methyl Methacrylate Initiated by 3-Acrylamide-9-Ethylcarbazole and Diphenyliodomium Salt[J]. Chemical Research, 2001, 12(1): 49-51
Authors:PAN Hui  ZHAO Ji-dong  GUAN Hui-li  LI Run-ming  GAO Qing-yu
Abstract:In this paper, the photopolymrization of methyl methacrylate initiated by 3_acrylamide_9_ethylcarbazole (AAECZ) and diphenyliodonium chloride salt was studied, the photopolymerization rate equation and its activation energies were obtained. The mechanism of initiation was discussed.
Keywords:acrylamide-9-ethylcarbazole  diphenyliodonium salt  methyl methacrylate  photopolymerization
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