| 3-丙烯酰胺基-9-乙基咔唑/碘鎓盐体系敏化甲基丙烯酸甲酯光聚合 |
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| 引用本文： | 潘卉,赵纪冬,关会立,李润明,高青雨.3-丙烯酰胺基-9-乙基咔唑/碘鎓盐体系敏化甲基丙烯酸甲酯光聚合[J].化学研究,2001,12(1):49-51. |
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| 作者姓名： | 潘卉 赵纪冬 关会立 李润明 高青雨 |
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| 作者单位： | 河南大学润滑与功能材料实验室, |
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| 基金项目： | 河南省自然科学基金!资助项目 ( 199915 0 0 2 5 ) |
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| 摘 要： | 研究了 3_丙烯酰胺基_9_乙基咔唑 (AAECZ) /氯化二苯基碘钅翁盐 (DPIOC)组成的光敏引发体系引发的甲基丙烯酸甲酯 (MMA)光聚合 ,并研究了各因素对聚合速率的影响 ,得到了聚合动力学方程 ;讨论了温度对聚合反应的影响 ,并探讨了引发机理
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| 关 键 词： | 3-丙烯酰胺基-9-乙基咔唑 二苯基碘鎓盐 甲基丙烯酸甲酯 光聚合 |
| 文章编号： | 1008-1011(2001)01-0049-03 |
| 修稿时间： | 2000年10月9日 |
The Photopolymerization of Methyl Methacrylate Initiated by 3-Acrylamide-9-Ethylcarbazole and Diphenyliodomium Salt |
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| PAN Hui,ZHAO Ji-dong,GUAN Hui-li,LI Run-ming,GAO Qing-yu.The Photopolymerization of Methyl Methacrylate Initiated by 3-Acrylamide-9-Ethylcarbazole and Diphenyliodomium Salt[J].Chemical Research,2001,12(1):49-51. |
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| Authors: | PAN Hui ZHAO Ji-dong GUAN Hui-li LI Run-ming GAO Qing-yu |
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| Abstract: | In this paper, the photopolymrization of methyl methacrylate initiated by 3_acrylamide_9_ethylcarbazole (AAECZ) and diphenyliodonium chloride salt was studied, the photopolymerization rate equation and its activation energies were obtained. The mechanism of initiation was discussed. |
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| Keywords: | acrylamide-9-ethylcarbazole diphenyliodonium salt methyl methacrylate photopolymerization |
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