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A remarkably simple N-formylation of anilines using polyethylene glycol
Authors:Biswanath Das  Maddeboina Krishnaiah  P Balasubramanyam  Boyapati Veeranjaneyulu  D Nandan Kumar
Institution:Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:N-Formylation of anilines has efficiently been carried out at room temperature in excellent yields by treatment with formic acid in polyethylene glycol (PEG-400). No additional solvent and catalyst are required.
Keywords:N-Formylation  Anilines  Formic acid  PEG-400  Catalyst- and solvent-free reaction
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