Specific heat related to the Raman frequency shifts for the rotatory mode in ammonia solid I close to the melting point |
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Authors: | H Karaçal? |
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Institution: | Department of Physics, Middle East Technical University, 06531 Ankara, Turkey |
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Abstract: | This study gives an evidence for the validity of our spectroscopic modification of the Pippard relation as applied to ammonia solid I close to the melting point. We use our calculated frequencies for the rotatory lattice (librational) mode in ammonia solid I for the pressures of 0, 1.93 and 3.07 kbars. We obtain that the specific heat Cp varies linearly with the frequency shifts 1/ν(∂ν/∂T)p for this Raman mode at those pressures studied in this crystalline system. Our values of the slope dPm/dT that we deduced from the linear plots, are not in satisfactory agreement with the experimental values in ammonia solid I near the melting point. |
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Keywords: | Ammonia solid I Raman frequciencies Melting point |
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