Synthesis,characterization and reactivity of a neutral antimony(III) complex |
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Authors: | Xiong Sun Congqing Zhu |
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Affiliation: | State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China |
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Abstract: | Pincer complexes are widely used in organometallic and coordination chemistry. The role of antimony as a central donor atom in pincer ligands has been extensively explored in recent years. Although phenylenediamine derived PXP (X = B, Al, C, Si, Ge, Sn, N) type ligands exhibit diverse reactivity, analogues species based on antimony have been reported less frequently. Herein, we report a new PSbP complex and evaluate its reactivity. These species will broaden the family of phenylenediamine derived pincer complexes. |
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Keywords: | Pincer ligand Antimony Phenylenediamine Coordination |
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