Ultalong nanowires self-assembled from a [b]-bisphenanthrene-fused azadipyrromethene |
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| Authors: | Wanle Sheng Zhangcui Wang Erhong Hao Lijuan Jiao |
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| Institution: | 1. Department of Chemistry, Bengbu Medical College, Bengbu 233030, China;2. The Key Laboratory of Functional Molecular Solids, Ministry of Education, School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China |
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| Abstract: | The 1D microwires based on π-extended azaBODIPY were successfully prepared and characterized for the first time. The bisphenanthrene-fused azaBPP-12C with four hydrophobic chains was prepared through de novo synthesis method involving the Suzuki reaction and subsequent oxidative ring-fused coupling. The microwires and aggregation behavior were studied using SEM, XRD and absorption spectroscopy. Finally, an H-type aggregation was confirmed in the solution process. |
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| Keywords: | AzaBODIPY Self-assembly H-aggregation Nanowire |
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