| Solvothermal Synthesis and Crystal Structure of a Layered Thioantimonate(Ⅲ) [C_4H_9NH_3]_2Sb_4S_7 |
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| 引用本文： | 朱爱美,贾定先,王鹏,张勇.Solvothermal Synthesis and Crystal Structure of a Layered Thioantimonate(Ⅲ) [C_4H_9NH_3]_2Sb_4S_7[J].结构化学,2007(11). |
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| 作者姓名： | 朱爱美 贾定先 王鹏 张勇 |
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| 作者单位： | Department of Chemistry and Chemical Engineering Suzhou University，Department of Chemistry and Chemical Engineering，Suzhou University，Department of Chemistry and Chemical Engineering，Suzhou University，Department of Chemistry and Chemical Engineering，Suzhou University，Suzhou 215123，China，Suzhou 215123，China，Suzhou 215123，China，Suzhou 215123，China |
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| 基金项目： | the Natural Science Foundation of Universities of Jiangsu Province (No. 05KJB150110) |
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| 摘 要： | An inorganic-organic hybrid thioantimonate(Ⅲ) CH3(CH2)3NH3]2Sb4S7 1 with layered structure was synthesized by solvothermal method. 1 crystallizes in the triclinic system,space group P1 with a=7.0124(11),b=11.919(2),c=14.879(3),α=108.791(3),β=102.441(3),γ=92.846(2)o,V=1140.1(3)3,Mr=859.71,Z=2,Dc=2.504 g/cm3,μ =5.324 mm-1,F(000)=804,S=1.013,the final R=0.0297 and wR=0.0618 for 3534 observed reflections with I > 2σ(I). 1 consists of C4H9NH3]+ cations and two-dimensional Sb4S7]n2n- anion which is composed of three SbS3 trigonal pyramids and one SbS4 unit joined by sharing common corners. The anionic layers are stacked perpendicularly to the c axis of the unit cell forming two-dimensional channels between the layers. The C4H9NH3]+ cations interdigitate in a bilayer and reside in the 2D channels leading to a sandwich-like arrangement of the anion and cations.
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Solvothermal Synthesis and Crystal Structure of a Layered Thioantimonate(Ⅲ) [C_4H_9NH_3]_2Sb_4S_7 |
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| ZHU Ai-Mei JIA Ding-Xian WANG Peng ZHANG Yong.Solvothermal Synthesis and Crystal Structure of a Layered Thioantimonate(Ⅲ) [C_4H_9NH_3]_2Sb_4S_7[J].Chinese Journal of Structural Chemistry,2007(11). |
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| Authors: | ZHU Ai-Mei JIA Ding-Xian WANG Peng ZHANG Yong |
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| Abstract: | An inorganic-organic hybrid thioantimonate(Ⅲ) CH3(CH2)3NH3]2Sb4S7 1 with layered structure was synthesized by solvothermal method. 1 crystallizes in the triclinic system,space group P1 with a=7.0124(11),b=11.919(2),c=14.879(3),α=108.791(3),β=102.441(3),γ=92.846(2)o,V=1140.1(3)3,Mr=859.71,Z=2,Dc=2.504 g/cm3,μ =5.324 mm-1,F(000)=804,S=1.013,the final R=0.0297 and wR=0.0618 for 3534 observed reflections with I > 2σ(I). 1 consists of C4H9NH3]+ cations and two-dimensional Sb4S7]n2n- anion which is composed of three SbS3 trigonal pyramids and one SbS4 unit joined by sharing common corners. The anionic layers are stacked perpendicularly to the c axis of the unit cell forming two-dimensional channels between the layers. The C4H9NH3]+ cations interdigitate in a bilayer and reside in the 2D channels leading to a sandwich-like arrangement of the anion and cations. |
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| Keywords: | solvothermal synthesis crystal structure two-dimensional channel thioantimonate |
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