A new ketone synthesis by palladium-catalyzed cross-coupling reactions of esters with organoboron compounds |
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Authors: | Tatamidani Hiroto Kakiuchi Fumitoshi Chatani Naoto |
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Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. |
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Abstract: | [reaction: see text] The palladium-catalyzed coupling reaction of 2-pyridyl esters with organoboron compounds is described. The reaction is compatible with various functional groups and proceeds under mild reaction conditions. The coordination of the nitrogen atom to Pd is a key step for efficient reaction. |
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