Controlled synthesis of thermoresponsive polymers derived from L-proline via RAFT polymerization |
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Authors: | Mori Hideharu Iwaya Hideyuki Nagai Atsushi Endo Takeshi |
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Institution: | Department of Polymer Science and Engineering, Faculty of Engineering, Yamagata University, Yonezawa, Japan. h.mori@yz.yamagata-u.ac.jp |
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Abstract: | Well-defined polymers derived from L-proline are synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization and the amino acid-based polymers exhibit thermosensitive phase separation at lower critical solution temperatures (LCST = 15-45 degrees C) in aqueous medium. |
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