Reactions of C-phosphorylated acetamidines with dialkylchlorophosphates |
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| Authors: | V. E. Shishkin E. V. Mednikov Yu. V. Popov M. A. Shevchenko O. V. Anishchenko E. V. Gurba Chau Nhat Bang B. D. Emenka |
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| Affiliation: | 1.Volgograd State Technical University,Volgograd,Russia |
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| Abstract: | The reactions of the C-phosphorylated acetamidines sodium derivatives with dialkylchlorophosphates were studied. They occur selectively to afford N 1,N 1-dialkyl-N 2-benzoylbis(dialkoxyphosphoryl)-acetamidines. Based on the CH-acid properties of C-phosphorylated acetamidines, we developed a convenient method for the synthesis of new diphosphorylated amidines. |
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