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Reactions of C-phosphorylated acetamidines with dialkylchlorophosphates
Authors:V E Shishkin  E V Mednikov  Yu V Popov  M A Shevchenko  O V Anishchenko  E V Gurba  Chau Nhat Bang  B D Emenka
Institution:1.Volgograd State Technical University,Volgograd,Russia
Abstract:The reactions of the C-phosphorylated acetamidines sodium derivatives with dialkylchlorophosphates were studied. They occur selectively to afford N 1,N 1-dialkyl-N 2-benzoylbis(dialkoxyphosphoryl)-acetamidines. Based on the CH-acid properties of C-phosphorylated acetamidines, we developed a convenient method for the synthesis of new diphosphorylated amidines.
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