synthesis and some transformations of 4-oxo-2-(β-ethoxyvinyl)-4H-1,3-benzoxazinium salts |
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Authors: | G N Dorofeenko V V Mezheritskii Yu I Ryabukhin O V Ivanova L G Minyaeva |
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Institution: | (1) Scientific-Research Institute of Physical and Organic Chemistry, Rostov State University, 344006 Rostov-on-Don |
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Abstract: | A method was developed for the synthesis of 4-oxo-(-ethoxyvinyl)-4H-1,3-benzoxazinium salts by condensation of oxo-2-alkylbenzoxazinium salts by condensation of oxo-2-alkylbenzoxazinium salts with ethyl orthoformate. During hydrolysis and aminolysis, attack of the nucleophile is directed to the -carbon atom of the benzoxazinium salts. The previously unknown 2-formylmethylene-4-oxo-3,4-dihydro-2H-1,3-benzoxazines and their nitrogen derivatives were obtained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 322–327, March, 1977. |
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