Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex |
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| Authors: | Hung Chen-Hsiung Wang Shan-Ling Ko Jia-Ling Peng Chih-Hsiung Hu Ching-Han Lee Ming-Tsung |
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| Affiliation: | Department of Chemistry, National Changhua University of Education, Changhua 50058 Taiwan. chhung@cc.ncue.edu.tw |
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| Abstract: | [structure: see text] The demetalation of M(III)(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH(-) to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)(2). |
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