Total syntheses of (+/-)-montanin A and (+/-)-teuscorolide |
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| Authors: | Chen I-Chia Wu Yen-Ku Liu Hsing-Jang Zhu Jiang-Liang |
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| Institution: | Department of Chemistry, National Tsing Hua University, Hsinchu, 30013, Taiwan. |
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| Abstract: | The first total syntheses of (+/-)-montanin A and (+/-)-teuscorolide have been achieved from an advanced precursor previously developed via a Diels-Alder strategy; in the synthetic sequence, the synthesis of montanin A was first accomplished in 8 steps, from which teuscorolide was readily achieved in 2 steps by using a novel furan oxidative cyclization-retro-cyclization process as a key operation. |
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