Octahedral rhenium(III) chalcocyanide cluster anions: Synthesis, structure, and solid state design |
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Authors: | N G Naumov A V Virovets V E Fedorov |
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Institution: | (1) Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USSR |
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Abstract: | The review summarizes data on synthesis and structure of rhenium chalcocyanide cluster onions Re6X8(CN)6]4-f (X = S, Se, Te) belonging to a new class of inorganic compounds. Two main groups of such compounds are considered: salts
with an island structure and polymer compounds. Various factors governing the type of structure and the dimensionality of
the polymer compounds are analyzed, including the nature of the chalcogen atom in the cluster anion, preferable coordination
of the transition metal cation, and the size of additional charge-compensating cations. Crystal-chemical approaches to design
of complex salts based on octahedral rhenium chalcocyanide cluster anions are formulated.
Translated fromZhurnal Strukturnoi Khimii, Vol. 41, No. 3, pp. 609-638, May–June, 2000. |
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