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A nanostructured skeleton catalyst: Suzuki-coupling with a reusable and sustainable nanoporous metallic glass Pd-catalyst
Authors:Tanaka Shinya  Kaneko Tetsuro  Asao Naoki  Yamamoto Yoshinori  Chen Mingwei  Zhang Wei  Inoue Akihisa
Affiliation:Center for Integrated NanoTechnology Support, Tohoku University, Sendai 980-8577, Japan.
Abstract:Nanoporous metallic glass Pd, which was fabricated by dealloying of a glassy metallic alloy Pd(30)Ni(50)P(20), exhibited a remarkable catalytic activity for the Suzuki-coupling reaction between iodoarenes and arylboronic acids under mild conditions. Moreover, the catalyst can be reused several times without a significant loss of catalytic activity.
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