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Two New Ceramides from the Marine Sponge Ircinia fasciculata
Authors:Guang‐Wen Zhang  Xiang‐Quan Ma  Cui‐Xian Zhang  Jing‐Yu Su  Wen‐Cai Ye  Xiao‐Qi Zhang  Xin‐Sheng Yao  Long‐Mei Zeng
Abstract:A new 4‐sulfated ceramide, ircisulfamide (=N‐(1S*,2S*,3R*)‐2‐hydroxy‐1‐(hydroxymethyl)‐3‐(sulfooxy)heptadecyl]hexadecanamide; 1 ), and a new glycosphingolipid, ircicerebroside (=(2R*)‐N‐{(1S*,2R*,3E,7E)‐1‐(β‐D ‐glucopyranosyloxy)methyl]‐2‐hydroxy‐8‐methylheptadeca‐3,7‐dienyl}‐2‐hydroxyeicosanamide; 2 ), were isolated from the aqueous EtOH extract of the marine sponge Ircinia fasciculata (Pallas ). The structures of the new compounds were elucidated on the basis of spectroscopic analysis and by means of chemical methods.
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