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New Synthesis of Ferrocene Monocarboxylic Acid and Systematic Studies on the Preparation of Related Key‐Intermediates
Authors:Alberto Federman Neto  Joseph Miller  Vnia Faria de Andrade  Susana Yumi Fujimoto  Mrcia Maísa de Freitas Afonso  Fernando Costa Archanjo  Vítor Andr Darin  Mrcio Luís Andrade e Silva   urea Donizete Lanchote Borges  Gino Del Ponte
Abstract:An improved technique for the preparation of ferrocenecarboxaldehyde and two new methods for the synthesis of ferrocenemonocarboxylic acid from the aldehyde or from acetyl ferrocene are described. Using the aldehyde or the monocarboxylic acid as starting materials, some important ferrocene key intermediates were prepared: monochlorocarbonyl ferrocene, alkali metal and ammonium ferrocenoates, ferrocene carboxyaldehyde diethylacetal, ferrocenecarboxamide, et …, as well as a new ferrocene derivative: piperazinium diferrocenoate.
Keywords:Ferrocene  Organometallics
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