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Weak segregation in molten statistical copolymers
Authors:Pierre-Gilles de Gennes
Affiliation:College de France, 11 place M. Berthelot, 75231 Paris Cedex 05, France, Fax: +33 1 45 35 14 74
Abstract:We present a qualitative argument suggesting that a statistical (AB) copolymer should display a certain form of weak segregation, with A rich and B rich regions of size comparable to the coil radius. This should occur if the Flory parameter χ is larger than unity (much larger than for the phase separation of A and B of homopolymers) in agreement with detailed calculations by Frederikson, Milner and Leibler. We achieve a certain qualitative insight for the resulting microphase.
Keywords:microphase separation  polymer melts  segregation  statistical copolymers
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