Abstract: | Formation of NH4Hg3(NH)2](NO3)3 and Transformation to Hg2N](NO3) NH4Hg3(NH)2](NO3)3 ( 1 ) and Hg2N](NO3) ( 2 ) are obtained from conc. aqueous ammonia solutions of Hg(NO3)2 at ambient temperature and under hydrothermal conditions at 180 °C, respectively, as colourless and dark yellow to light brown single crystals. The crystal structures {NH4Hg3(NH)2](NO3)3: cubic, P4132, a = 1030.4(2) pm, Z = 4, Rall = 0.028; Hg2N](NO3): tetra gonal, P43212, a = 1540.4(1), c = 909.8(1) pm, Z = 4, Rall = 0.054} have been determined from single crystal data. Both exhibit network type structures in which HNHg3] and NHg4] tetrahedra of the partial structures of 1 and 2 are connected via three and four vertices, respectively. 1 transforms at about 270 °C in a straightforward reaction to 2 whereby the decomposition products of NH4NO3 are set free. 2 decomposes at about 380 °C forming yellow HgO. Most certainly, 1 is identical with a mineral previously analyzed as “Hg(NH2)(NO3)” with the same Hg:N:O ratio. |