| Abstract: | 1,2‐Diorganylsubstituted derivatives of hydrazinium azide were examined in order to investigate their higher volatility and higher sensitivity to initiation compared to 1,1‐diorganylsubstituted hydrazinium azide derivatives. The compounds were synthesized from the respective hydrazines by reaction with HN3 and characterized by elemental analysis, vibrational (IR, Raman) and multinuclear NMR spectroscopy (1H, 13C, 14N). Their sensitivity to friction, shock, electrostatic impact and heat was examined and the explosion products were investigated. The crystal structure of pyrazolidinium azide was determined. |
