Die Kristallstruktur von [InI · C6D6][{(CH3)3Si}3C‐InI3]; ein Nebenprodukt der Umsetzung von InI3 mit basefreiem Li‐C(Si(CH3)3)3 |
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Authors: | T Viefhaus W Schwarz J Weidlein |
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Abstract: | The title compound is formed together with LiTsi‐InI3] (the main product), (Tsi‐In(Me)I)2 and (Tsi)2InMe in very low yield in the reaction of InI3 with Tsi‐Li (Tsi = ‐C(Si(CH3)3)3)in toluene. According to the X‐ray structure determination this compound crystallizes in the triclinic space group P&1marc; and consists of slightly associated dimers of Tsi‐InI3]‐ anions via weak InI···I(‐InIII) contact‐bonds of 345.6(1) to 373.8(2) pm. Additionally the InI atom is capped by a D6‐benzene molecule. |
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Keywords: | Tris(trimethylsilyl)methyl compound Indium Crystal structure |
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