| Abstract: | Synthesis and Crystal Structure of C(NMe2)3]2(CO)4Fe(μ‐InCl2)2Fe(CO)4] Treatment of C(NMe2)3]2(CO)4FeInCl3] ( 1 ) with hot water produces the dinuclear complex C(NMe2)3]2(CO)4Fe(μ‐InCl2)2Fe(CO)4] ( 2 ) which could be crystallized from dichloromethane/pentane. 2 crystallizes in the monoclinic space group P21/n with a = 835.7(1), b = 1187.8(1), c = 1902.7(1) pm, β = 91.877(5)° and Z = 2. The anion contains a four‐membered Fe—In—Fe—In ring with octahedral environment at the iron atom and tetrahedral coordination at the In atom. |
