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Photoinduced Isomerization of Potassium Polyfluoroalk‐1‐enyltrifluoroborates |
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| Authors: | V V Bardin H‐J Frohn |
| Abstract: | The UV irradition of K RCF=CFBF3] R = C4F9 (trans), C2F5 (cis), C6F13 (cis), Cl (cis/trans 1 : 1)] in acetone led to cis/trans‐isomerization with a final cis/trans composition 7 : 3. In the case of R = C4H9 (trans) or C3F7O (cis/trans 25 : 75) the photoisomerization was accompanied by a partial decomposition. |
| Keywords: | Borates Isomerization Fluoroalkenylborates Fluoroborates |