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Creep relaxation and stress relaxation of PS-HI/SEBS blends
Authors:Vesna Rek  Tamara Holjevac Grgurić  Želimir Jelčić
Affiliation:1. Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg19, Zagreb, Croatia;2. DIOKI d.o.o., Žitnjak bb., Zagreb, Croatia
Abstract:For the selection of the polymer materials and polymer blends for various fields of applications the stability of material under constant deformation and constant load are very important. In this paper, the copolymers high-impact polystyrene, PS-HI, styrene-ethylene/buthylene-styrene block copolymer, SEBS, and their blends PS-HI/SEBS were investigated. The investigations were done by DMA analysis. The secondary viscoelastic functions, creep, creep modulus, stress and flexural relaxation modulus were investigated in creep and stress relaxation experiment at temperatures 25, 35, 45, 55 and 65°C during 1 h. The master curves were created by time-temperature correspondence principle, TTC. The correlation of the secondary viscoelastic functions with time, temperature and content of the hard, PS, phase was discussed.
Keywords:creep  dynamic-mechanical behavior  high-impact polystyrene  master curve  PS-HI/SEBS blends  stress relaxation  styrene-ethylene/butylene-styrene block copolymer  time-temperature superposition
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