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Syntheses and Structures of Zinc(II) Co‐Ordination Polymers Bridged by Flexible Bidentate Nitrogen Ligands |
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| Authors: | Maw‐Cherng Suen Ymg‐Yann Wu Guo‐Chung Dong Jhy‐Der Chen Tai‐Chiun Keng Ju‐Chun Wang |
| Abstract: | The reaction of Zn(NO3)2·6H2O and bpp (bpp = 1,3‐Bis(4‐pyridyl)pronpane) in CH3OH afforded the complex Zn(bpp)(NO3)2]n, 1 . The IR has been recorded and the structure has been determined. Crystal data for 1: Space group P2(1)/n, a = 11.749(1), b = 11.413(1), c = 11.942(1) Å, β = 96.06(6)°. V = 1592.5(3) Å3, Z = 4 with final residuals R1 = 0.0484 and wR2 = 0.0984. The complexes show supramolecular structure in the solid state by intermolecular hydrogen bonding interaction. |
| Keywords: | Supramolecular Zigzag‐chain gauche‐anti Self‐assembly |