Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles |
| |
Authors: | Lubriks Dmitrijs Sokolovs Igors Suna Edgars |
| |
Affiliation: | Latvian Institute of Organic Synthesis, Aizkraukles 21, LV-1006, Riga, Latvia. |
| |
Abstract: | A mild, room-temperature Pd-catalyzed acetoxylation of pyrroles with phenyliodonium acetate is described. The acetoxylation was found to proceed via the initial formation of pyrrolyl(phenyl)iodonium acetates, which were converted to acetoxypyrroles in the presence of Pd(OAc)(2). The acetoxylation could also be carried out as a one-pot sequential procedure without the isolation of the intermediate iodonium salts. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|