| 氧化碘苯间氨基苯甲酸锰(IV)四苯基卟啉配合物的合成 |
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| 引用本文： | 金日镇,高桂芬,金范龙.氧化碘苯间氨基苯甲酸锰(IV)四苯基卟啉配合物的合成[J].化学学报,1987,45(1):68-70. |
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| 作者姓名： | 金日镇 高桂芬 金范龙 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 高价锰卟啉配合物在温和条件下分解水,释放氧,是植物光体体II的可能模型化合物.我们选择间氨基苯甲酸作为轴向配体,在二氯甲烷中用氧化碘苯氧化H2NC6H4COOMn(III)TPP
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| 关 键 词： | 紫外分光光度法 氨基酸 卟吩P 红外分光光度法 电子自旋共振谱法 苯P 氯仿 苯甲酸P 结构分析 锰络合物 |
Synthesis of iodosylbenzene, m-aminobenzoic acid tetraphenylprophinato manganese(IV) |
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| JIN RIZHEN,GAO GUIFEN,JIN FANLONG.Synthesis of iodosylbenzene, m-aminobenzoic acid tetraphenylprophinato manganese(IV)[J].Acta Chimica Sinica,1987,45(1):68-70. |
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| Authors: | JIN RIZHEN GAO GUIFEN JIN FANLONG |
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| Abstract: | MnIV(m-O2CC6H4NH2)(TPP)(OIPh) (I, H2TPP = tetraphenylpropphyrin) was prepared by the oxidation of MnIII(m-O2CC6H4NH2)(TPP) in CH2Cl2 with iodosylbenzene. The visible absorption spectrum of I has an intense Soret band at 422 nm and a broad shoulder band at 522 nm. The IR spectrum has an intense absorption band at 580 cm-1 which is assigned to a Mn-O-O stretch and an absorption band at 1630 cm-1 which is assigned to the asym. stretching vibrations of carboxylate group. The ESR spectrum has a broad absorption band at g = 2.00 and an intense absorption band at ge^ = 3.26. |
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| Keywords: | ULTRAVIOLET SPECTROPHOTOMETRY AMINO ACID PORPHINE P INFRARED SPECTROPHOTOMETRY ELECTRON SPIN RESONANCE SPECTROMETRY BENZENE P CHLOROFORM BENZENECARBOXYLIC ACID P STRUCTURAL ANALYSIS MANGANESE COMPLEX |
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