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Bicyclo[3.2.1]octenones As Building Blocks in Natural Products Synthesis (III). Total Synthesis of (±)-10-Deoxygeniposide Aglucone |
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| Authors: | Lung-Fu Hsu Nein-Chen Chang |
| Abstract: | The title compound was synthesized from bicyclo[3.2.1]octenone 1 in six steps and in overall yield 59%. Photochemical rearrangement of β,γ-unsaturated enone 1 is the key step. |
| Keywords: | Iridoids Bicyclo[3.2.1]octenones Bicyclo-[3.3.0]octenoncs (± )-10-Deoxygeniposide aglucone Photochemical rearrangement of β ,γ -unsaturated ketone Cyclopentanpyran Monoterpenes |