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Diastereoselective Alkylation of (Diene-Aldehyde)Fe(CO)3 Complexes with Functionalized Zinc-Copper Reagents NuCu(CN)Znl
Authors:Jeng-Long Wang  Chuen-Her Ueng  Ming-Chang P. Yeh
Abstract:Addition of functionalized zinc-copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X-ray diffraction analysis.
Keywords:Diastereoselective alkylation  (Diene-aldehyde)Fe(CO)3 complex  Functionalized zinc-copper reagents  Diastereomeric ratio
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